Abstract
Construction of the left segment of azadirachtin in naturally occurring enantiomer is described. The key reaction is an intramolecular Diels-Alder reaction, which was performed under thermal conditions to afford the highly functionalized decalin compounds selectively.
| Original language | English |
|---|---|
| Pages (from-to) | 4387-4390 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 40 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 1999 Jun 4 |
Keywords
- Azadirachtin
- Decalin
- Diels-Alder reaction
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Ishihara, J., Yamamoto, Y., Kanoh, N., & Murai, A. (1999). Synthetic studies on azadirachtin: Construction of the highly functionalized decalin moiety of azadirachtin. Tetrahedron Letters, 40(23), 4387-4390. https://doi.org/10.1016/S0040-4039(99)00755-8