Abstract
The detailed examination of intramolecular Diels-Alder reactions of several structurally related trienes led to construction of the desired tricyclic decalin moiety of azadirachtin with the α-hydroxyl groups at C1 and C3 as well as the oxygenated substituent at C8 in the naturally occurring form in good yields.
Original language | English |
---|---|
Pages (from-to) | 1894-1906 |
Number of pages | 13 |
Journal | Synthesis |
Issue number | 13 |
DOIs | |
Publication status | Published - 2000 Jan 1 |
Keywords
- Azadirachtin
- Cyclic carbonate
- Decalin
- Insect antifeedant
- Intramolecular Diels-Alder reaction
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry