Synthesis, structures, and optical properties of heteroarene-fused dispiro compounds

Toshiyuki Kowada, Toshihisa Kuwabara, Kouichi Ohe

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

(Chemical Equation Presented) Novel heteroarene-fused dispiro compounds, dispiro[9H-fluorene-9,5′(6′H)-diindeno[1,2-b:2′,1′-d] -furan-6′,9″-[9H]fluorene] (dsp-DIF), dispiro[9H-fluorene-9, 5′(6′H)-diindeno[1,2-b:2′,1′-d]thiophene-6′, 9″-[9H]fluorene] (dsp-DIT), and 11-phenyldispiro[9H-fluorene-9, 5′(6′H)-diindeno[1,2-b:2′,1′-d]pyrrole-6′, 9″-[9H]fluorene] (dsp-DIP-Ph) have been synthesized. Their structures were unambiguously determined by X-ray crystallography. These three dispiro compounds showed blue fluorescence with moderate quantum yields.

Original languageEnglish
Pages (from-to)906-913
Number of pages8
JournalJournal of Organic Chemistry
Volume75
Issue number3
DOIs
Publication statusPublished - 2010 Feb 5
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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