Synthesis, structure, and redox properties of diphosphathienoquinones

Fumiki Murakami, Shigeru Sasaki, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The first diphosphaheteroquinoid compound, which contains two low-coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air-stable orange crystals. Its quinoid nature was confirmed by x-ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.

Original languageEnglish
Pages (from-to)2574-2576
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number14
DOIs
Publication statusPublished - 2002 Jul 15

Keywords

  • Phosphaalkenes
  • Quinones
  • Radical ions
  • Redox chemistry
  • Sulfur heterocycles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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