Synthesis, structure, and reactivities of the η1η62-aryl alkynyl diruthenium complex. X-ray structure of [Cp(PPh3)2Ru(η1η62 -C≡CC6H4Me-p)RuCp*]PF6 (Cp = η5-C5H5, Cp * = η5-C5Me5)

Hiroyuki Matsuzaka, Yoshiyuki Sato, Hironobu Okimura, Tomohiko Ishii, Masahiro Yamashita, Susumu Kitagawa, Mitsuru Kondo, Moto O. Shiro, Mikio Yamasaki

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Preparation of a η16-μ2-aryl alkynyl diruthenium complex [CP(PPh3)2Ru(η16-μ2-C≡CC6H4Me-P)RuCp*JCl (2•Cl) [Cp = η5-C5H5, Cp* = η5-C5Me5] and its reactions with electrophile or CO are reported. The structure of 2•PF6 has been determined by X-ray crystallography.

Original languageEnglish
Pages (from-to)865-866
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - 1999 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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