Synthesis, structure, and properties of three- and six-membered metallacycles composed of iron, germanium, and sulfur atoms

Masaaki Okazaki; Hiromitsu Kimura; Takashi Komuro; Hiroshi Okada; Hiromi Tobita

doi:10.1246/cl.2007.990

Synthesis, structure, and properties of three- and six-membered metallacycles composed of iron, germanium, and sulfur atoms

Masaaki Okazaki, Hiromitsu Kimura, Takashi Komuro, Hiroshi Okada, Hiromi Tobita

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Ultraviolet irradiation of Cp* (CO)₂FeGeMe₂ SPh in the presence of acetone afforded trans-[Cp*Fe(CO) {μ- κ²Ge, S-GeMe₂SPh}]₂, while the introduction of a bulkier substituent on the sulfur atom allowed selective formation of the three-membered metallacycle Cp*(CO) Fe{κ²Ge,S-GeMe₂SMes} (Mes = 2,4,6-C ₆H₂Me₃).

Original language	English
Pages (from-to)	990-991
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	8
DOIs	https://doi.org/10.1246/cl.2007.990
Publication status	Published - 2007 Aug 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2007.990

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title = "Synthesis, structure, and properties of three- and six-membered metallacycles composed of iron, germanium, and sulfur atoms",

abstract = "Ultraviolet irradiation of Cp* (CO)2FeGeMe2 SPh in the presence of acetone afforded trans-[Cp*Fe(CO) {μ- κ2Ge, S-GeMe2SPh}]2, while the introduction of a bulkier substituent on the sulfur atom allowed selective formation of the three-membered metallacycle Cp*(CO) Fe{κ2Ge,S-GeMe2SMes} (Mes = 2,4,6-C 6H2Me3).",

author = "Masaaki Okazaki and Hiromitsu Kimura and Takashi Komuro and Hiroshi Okada and Hiromi Tobita",

year = "2007",

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doi = "10.1246/cl.2007.990",

language = "English",

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journal = "Chemistry Letters",

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T1 - Synthesis, structure, and properties of three- and six-membered metallacycles composed of iron, germanium, and sulfur atoms

AU - Okazaki, Masaaki

AU - Kimura, Hiromitsu

AU - Komuro, Takashi

AU - Okada, Hiroshi

AU - Tobita, Hiromi

PY - 2007/8/5

Y1 - 2007/8/5

N2 - Ultraviolet irradiation of Cp* (CO)2FeGeMe2 SPh in the presence of acetone afforded trans-[Cp*Fe(CO) {μ- κ2Ge, S-GeMe2SPh}]2, while the introduction of a bulkier substituent on the sulfur atom allowed selective formation of the three-membered metallacycle Cp*(CO) Fe{κ2Ge,S-GeMe2SMes} (Mes = 2,4,6-C 6H2Me3).

AB - Ultraviolet irradiation of Cp* (CO)2FeGeMe2 SPh in the presence of acetone afforded trans-[Cp*Fe(CO) {μ- κ2Ge, S-GeMe2SPh}]2, while the introduction of a bulkier substituent on the sulfur atom allowed selective formation of the three-membered metallacycle Cp*(CO) Fe{κ2Ge,S-GeMe2SMes} (Mes = 2,4,6-C 6H2Me3).

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DO - 10.1246/cl.2007.990

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 8

ER -

Synthesis, structure, and properties of three- and six-membered metallacycles composed of iron, germanium, and sulfur atoms

Abstract

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