Synthesis, structure, and photoluminescence of a novel oxynitride baysi2o5n activated by Eu2+ and Ce3+

Makoto Kobayashi, Takuya Yasunaga, Hironori Sato, Hideki Kato, Kotaro Fujii, Masatomo Yashima, Masato Kakihana

    Research output: Contribution to journalArticlepeer-review

    6 Citations (Scopus)

    Abstract

    A novel oxynitride, BaYSi2O5N, has been synthesized by a solid-state reaction method. Its crystal structure was determined by single-crystal X-ray analysis. Eu2+- and Ce3+-doped BaYSi2O5N exhibit broad blue emission with peaks around 459 and 412 nm under excitation at 250-450 and 250-370 nm, respectively. This is the first report on the synthesis of oxynitrides in the BaO-Y2O3-SiO2-Si3N4 system.

    Original languageEnglish
    Pages (from-to)795-797
    Number of pages3
    JournalChemistry Letters
    Volume46
    Issue number6
    DOIs
    Publication statusPublished - 2017

    Keywords

    • Novel compound
    • Oxynitride
    • Phosphor

    ASJC Scopus subject areas

    • Chemistry(all)

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