Abstract
The icosahedral boron clusters, carboranes (closo-C2B 10H12) can be considered as three-dimensional aromatic systems. We have been studying magnetic properties of carboranyl radicals, and ortho-carboranyl biradical containing nitronylnitroxide arms (OCB-BNN) has been already reported. In this presentation, we would like to report weta-carboranyl biradical (MCB-BNN) containing same radical units for the purpose of the investigation of the magnetic interaction of the structure isomer. The synthesis, X-ray crystal structure and magnetic behaviors in solution and crystalline phase of MCB-BNN will be presented.
Original language | English |
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Number of pages | 1 |
Publication status | Published - 2006 Oct 19 |
Event | 55th SPSJ Annual Meeting - Nagoya, Japan Duration: 2006 May 24 → 2006 May 26 |
Other
Other | 55th SPSJ Annual Meeting |
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Country | Japan |
City | Nagoya |
Period | 06/5/24 → 06/5/26 |
Keywords
- Carborane
- Magnetic property
- Molecular magnetism
- Nitronyl nitroxide
ASJC Scopus subject areas
- Engineering(all)