Synthesis, structure and magnetic property of novel carboranyl radicals

Kazunari Matsumura, Fumiyasu Iwahori, Masahiro Yamashita, Jiro Abe

Research output: Contribution to conferencePaperpeer-review

Abstract

The icosahedral boron clusters, carboranes (closo-C2B 10H12) can be considered as three-dimensional aromatic systems. We have been studying magnetic properties of carboranyl radicals, and ortho-carboranyl biradical containing nitronylnitroxide arms (OCB-BNN) has been already reported. In this presentation, we would like to report weta-carboranyl biradical (MCB-BNN) containing same radical units for the purpose of the investigation of the magnetic interaction of the structure isomer. The synthesis, X-ray crystal structure and magnetic behaviors in solution and crystalline phase of MCB-BNN will be presented.

Original languageEnglish
Number of pages1
Publication statusPublished - 2006 Oct 19
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: 2006 May 242006 May 26

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period06/5/2406/5/26

Keywords

  • Carborane
  • Magnetic property
  • Molecular magnetism
  • Nitronyl nitroxide

ASJC Scopus subject areas

  • Engineering(all)

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