Abstract
Three-spin magnetic cluster consists of manganese(II) and ortho-carboranyl biradical OCB-BNN have been synthesized and characterized as the first example of the carborane containing paramagnetic complex. The crystal structure of discrete 1:1 complex Mn(hfac)2·OCB-BNN was unambiguously determined. In the crystal structure, OCB-BNN behaves as the molecular tweezers that bind to manganese(II) ion. The strong antiferromagnetic interaction (J/kB = -181(2) K) was found between nitronyl nitroxides and manganese(II) ion.
Original language | English |
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Pages (from-to) | 68-69 |
Number of pages | 2 |
Journal | Chemistry Letters |
Volume | 35 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2006 Jan 5 |
ASJC Scopus subject areas
- Chemistry(all)