Synthesis, structure and magnetic properties of the antiferromagnetic hexamanganese cluster [Mn64-O)2(O 2CC6HF4)10 (HO2CCH 3)4]·(C7H8)

Kazuya Nakata, Hitoshi Miyasaka, Tomohiko Ishii, Masahiro Yamashita, Kunio Awaga

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A hexanuclear MnII-MnIII-cluster, [Mn 6(O)2(O2CC6HF4) 10(HO2CCH3)4]·(C 7H8) (1), was synthesized by a typical acetate-substitution reaction of the well-known Mn12-cluster, [Mn12(O)12(O2CCH3) 16(H2O)4]·2CH3CO 2H·4H2O in the presence of an excess of 2, 3, 5, 6-tetrafluorobenzoic acid. Each unpaired spin on Mn(II) and Mn(III) ions is promoted as to be antiferromagnetically cancelled to produce an S = 0 ground state.

Original languageEnglish
Pages (from-to)211-216
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume379
DOIs
Publication statusPublished - 2002 Jan 1

Keywords

  • Antiferromagnetic interaction
  • Magnetic properties
  • Manganese cluster
  • Single-molecule magnets

ASJC Scopus subject areas

  • Condensed Matter Physics

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