Synthesis of unsymmetrically substituted 2,2’-dihydroxy-1,1’-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

Masahiro Terada, Katsunori Dan

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2’-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.

Original languageEnglish
Pages (from-to)5781-5783
Number of pages3
JournalChemical Communications
Volume48
Issue number46
DOIs
Publication statusPublished - 2012 May 14

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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