Synthesis of unsymmetrically substituted 2,2’-dihydroxy-1,1’-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

Masahiro Terada; Katsunori Dan

doi:10.1039/c2cc31594g

Synthesis of unsymmetrically substituted 2,2’-dihydroxy-1,1’-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

Masahiro Terada, Katsunori Dan

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2’-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.

Original language	English
Pages (from-to)	5781-5783
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	46
DOIs	https://doi.org/10.1039/c2cc31594g
Publication status	Published - 2012 May 14

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2{\textquoteright}-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.",

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AU - Dan, Katsunori

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Y1 - 2012/5/14

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AB - A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2’-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.

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Synthesis of unsymmetrically substituted 2,2’-dihydroxy-1,1’-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

Abstract

ASJC Scopus subject areas

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