Abstract
RhH(PPh3)4 and 1,2-bis(diphenylphosphino)benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the reaction of symmetrical polyfluorinated diaryl sulfides and substituted pentafluorobenzenes in the presence of triisopropylsilane.
Original language | English |
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Pages (from-to) | 4327-4329 |
Number of pages | 3 |
Journal | Tetrahedron Letters |
Volume | 54 |
Issue number | 32 |
DOIs | |
Publication status | Published - 2013 Aug 7 |
Keywords
- Aryl exchange reaction
- Pentafluorobenzenes
- Rhodium catalyst
- Symmetrical polyfluorinated diaryl sulfides
- Unsymmetrical polyfluorinated diaryl sulfides
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry