Synthesis of tricyclo[3.1.0.02,4]hexasilane and its photochemical isomerization to tricyclo[2.2.0.02,5]hexasilane

Takeaki Iwamoto, Kei Uchiyama, Chizuko Kabuto, Mitsuo Kira

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The first anti-tricyclo[3.1.0.02,4]hexasilane 1 was synthesized as pale yellow crystals. Irradiation (λ > 370 nm) of 1 gave its skeletal isomer, tricyclo[2.2.0.02,5]hexasilane 2, in 80% yield. The photochemical [σ2s + σ2S] cycloreversion of 1 followed by the thermal [π2S + π2a] cycloaddition to 2 would explain the overall isomerization.

Original languageEnglish
Pages (from-to)368-369
Number of pages2
JournalChemistry Letters
Volume36
Issue number3
DOIs
Publication statusPublished - 2007 Mar 5

ASJC Scopus subject areas

  • Chemistry(all)

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