Abstract
The electron-doped bismuth oxide (Ba0.6Bi0.4)BiO2.92 has been successfully synthesized by the two-step heating method. Mixed powders of the starting materials have been pelletized and heated in flowing gas of N2 at 800 °C for 12 h. The reacted pellets have been heated at 400 °C first in flowing gas of O2 for 24 h and then under a high oxygen-pressure of 600 atm at 400 °C for 96 h. It has crystallized in a pseudo-cubic symmetry. From the X-ray diffraction and inductively coupled plasma analyses, the substitution of Bi for Ba has been confirmed, but the product has still remained an insulator.
Original language | English |
---|---|
Pages (from-to) | 449-450 |
Number of pages | 2 |
Journal | Physica C: Superconductivity and its applications |
Volume | 388-389 |
DOIs | |
Publication status | Published - 2003 May |
Event | proceedings of the 23rd international conference on low temper - Hiroshima, Japan Duration: 2002 Aug 20 → 2002 Aug 27 |
Keywords
- Bismuth oxide
- Electron doping
- Perovskite
- Substitution
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Energy Engineering and Power Technology
- Electrical and Electronic Engineering