Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad

Taniyuki Furuyama; Yusuke Sugiya; Nagao Kobayashi

doi:10.6060/mhc140488k

Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad

Taniyuki Furuyama, Yusuke Sugiya, Nagao Kobayashi

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.

Original language	English
Pages (from-to)	139-144
Number of pages	6
Journal	Macroheterocycles
Volume	7
Issue number	2
DOIs	https://doi.org/10.6060/mhc140488k
Publication status	Published - 2014

Keywords

Absorption spectra
Subphthalocyanine
Tetrabenzotriazacorrole
μ-oxo-oligomer

ASJC Scopus subject areas

Analytical Chemistry
Organic Chemistry

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title = "Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad",

abstract = "A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.",

keywords = "Absorption spectra, Subphthalocyanine, Tetrabenzotriazacorrole, μ-oxo-oligomer",

author = "Taniyuki Furuyama and Yusuke Sugiya and Nagao Kobayashi",

year = "2014",

doi = "10.6060/mhc140488k",

language = "English",

volume = "7",

pages = "139--144",

journal = "Macroheterocycles",

issn = "1998-9539",

publisher = "Ivanovo State University of Chemistry and Technology",

number = "2",

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TY - JOUR

T1 - Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad

AU - Furuyama, Taniyuki

AU - Sugiya, Yusuke

AU - Kobayashi, Nagao

PY - 2014

Y1 - 2014

N2 - A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.

AB - A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.

KW - Absorption spectra

KW - Subphthalocyanine

KW - Tetrabenzotriazacorrole

KW - μ-oxo-oligomer

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DO - 10.6060/mhc140488k

M3 - Article

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SP - 139

EP - 144

JO - Macroheterocycles

JF - Macroheterocycles

SN - 1998-9539

IS - 2

ER -

Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad

Abstract

Keywords

ASJC Scopus subject areas

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