Abstract
A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.
Original language | English |
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Pages (from-to) | 139-144 |
Number of pages | 6 |
Journal | Macroheterocycles |
Volume | 7 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2014 |
Keywords
- Absorption spectra
- Subphthalocyanine
- Tetrabenzotriazacorrole
- μ-oxo-oligomer
ASJC Scopus subject areas
- Analytical Chemistry
- Organic Chemistry