Synthesis of tetrabenzotriazacorrole-subphthalocyanine μ-oxo triad

Taniyuki Furuyama, Yusuke Sugiya, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A μ-oxo-linked subphthalocyanine (SubPc)-tetrabenzotriazacorrole (TBC)-SubPc triad has been synthesized. The desired triad could be formed using axial ligand coupling between a TBC phosphorus(V) complex and SubPc, and was characterized by MS, 1H and 31P NMR spectra. The triad can absorb light across the entire UV-vis region. Spectroscopic and theoretical analyses support the proposal that the TBC chromophore interacts with the SubPc chromophore.

Original languageEnglish
Pages (from-to)139-144
Number of pages6
JournalMacroheterocycles
Volume7
Issue number2
DOIs
Publication statusPublished - 2014

Keywords

  • Absorption spectra
  • Subphthalocyanine
  • Tetrabenzotriazacorrole
  • μ-oxo-oligomer

ASJC Scopus subject areas

  • Analytical Chemistry
  • Organic Chemistry

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