Synthesis of rare earth niobate and tantalate powders via a peroxo complex route

Hideki Kato; Katsuya Shimizu; Kiyotaka Nakajima; Makoto Kobayashi; Masato Kakihana

doi:10.1246/cl.170652

Synthesis of rare earth niobate and tantalate powders via a peroxo complex route

Hideki Kato, Katsuya Shimizu, Kiyotaka Nakajima, Makoto Kobayashi, Masato Kakihana

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Powders of REMO₄ (RE: rare earth, M: Nb and Ta) were synthesized by a coprecipitation method employing watersoluble peroxo Nb/Ta complexes. This peroxo-based method is an aqueous solution route free from organics and halides. REMO₄ was directly crystallized by annealing the precursor under moderate conditions. It has been revealed that the precursors are also useful for synthesis of oxynitrides under mild nitriding conditions.

Original language	English
Pages (from-to)	1515-1517
Number of pages	3
Journal	Chemistry Letters
Volume	46
Issue number	10
DOIs	https://doi.org/10.1246/cl.170652
Publication status	Published - 2017

Keywords

Aqueous solution process
Peroxo complex method
Rare earth niobate/tantalate

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.170652

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title = "Synthesis of rare earth niobate and tantalate powders via a peroxo complex route",

abstract = "Powders of REMO4 (RE: rare earth, M: Nb and Ta) were synthesized by a coprecipitation method employing watersoluble peroxo Nb/Ta complexes. This peroxo-based method is an aqueous solution route free from organics and halides. REMO4 was directly crystallized by annealing the precursor under moderate conditions. It has been revealed that the precursors are also useful for synthesis of oxynitrides under mild nitriding conditions.",

keywords = "Aqueous solution process, Peroxo complex method, Rare earth niobate/tantalate",

author = "Hideki Kato and Katsuya Shimizu and Kiyotaka Nakajima and Makoto Kobayashi and Masato Kakihana",

note = "Funding Information: This work was partly supported by KAKENHI Grant Numbers JP24107004 and JP16H04186, the Cooperative Research Program of Institute for Catalysis, Hokkaido University (Grant #16B1003 and 17B1004), and the Research Program of “Five-star Alliance” in “NJRC Mater. & Dev.”",

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doi = "10.1246/cl.170652",

language = "English",

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T1 - Synthesis of rare earth niobate and tantalate powders via a peroxo complex route

AU - Kato, Hideki

AU - Shimizu, Katsuya

AU - Nakajima, Kiyotaka

AU - Kobayashi, Makoto

AU - Kakihana, Masato

N1 - Funding Information: This work was partly supported by KAKENHI Grant Numbers JP24107004 and JP16H04186, the Cooperative Research Program of Institute for Catalysis, Hokkaido University (Grant #16B1003 and 17B1004), and the Research Program of “Five-star Alliance” in “NJRC Mater. & Dev.”

PY - 2017

Y1 - 2017

N2 - Powders of REMO4 (RE: rare earth, M: Nb and Ta) were synthesized by a coprecipitation method employing watersoluble peroxo Nb/Ta complexes. This peroxo-based method is an aqueous solution route free from organics and halides. REMO4 was directly crystallized by annealing the precursor under moderate conditions. It has been revealed that the precursors are also useful for synthesis of oxynitrides under mild nitriding conditions.

AB - Powders of REMO4 (RE: rare earth, M: Nb and Ta) were synthesized by a coprecipitation method employing watersoluble peroxo Nb/Ta complexes. This peroxo-based method is an aqueous solution route free from organics and halides. REMO4 was directly crystallized by annealing the precursor under moderate conditions. It has been revealed that the precursors are also useful for synthesis of oxynitrides under mild nitriding conditions.

KW - Aqueous solution process

KW - Peroxo complex method

KW - Rare earth niobate/tantalate

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Synthesis of rare earth niobate and tantalate powders via a peroxo complex route

Abstract

Keywords

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