Synthesis of porous γ-Fe2O3 via alkaline treatment of size controlled scorodite particles synthesized using ultrasound irradiation and its evaluation as a cathode for lithium-ion battery

Yuya Kitamura, Hirokazu Okawa, Kozo Shinoda, Takahiro Kato, Katsuyasu Sugawara, Shigeru Suzuki

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Herein, we synthesized scorodite particles using ultrasound irradiation in a strong sulfuric acidic solution (pH 0.5) and investigated the scorodite particles' size and morphology. The highest crystallinity of scorodite (96%) was synthesized using 200 kHz ultrasonic treatment, and maximum yield of scorodite was obtained in three conditions: 200, 28 kHz, and stirrer. The oxidant generated through 200 kHz ultrasound irradiation enhanced Fe(II) oxidation in the solution resulting in crystal nuclei formation. The crystal nuclei were transformed to scorodite by oxidation with a supply of solute [Fe(III)] from the solution and ostwald ripening. Clustered scorodite (4 μm in size) was obtained via synthesis using 200 kHz ultrasound (pH 0.5). Arsenic could be separated from the clustered scorodite via alkaline treatment; scorodite was changed to porous γ-Fe2O3 comprising nanosized particles. Porous γ-Fe2O3 was evaluated as a cathode in a lithium-ion battery, which showed a 149 mAh g-1 discharge capacity with a 0.5 C rate.

Original languageEnglish
Article numberSGGD03
JournalJapanese journal of applied physics
Volume58
Issue numberSG
DOIs
Publication statusPublished - 2019

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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