Synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities

Takahiro Takei; Qiang Dong; Yoshinori Yonesaki; Nobuhiro Kumada; Nobukazu Kinomura

doi:10.3390/polym3010001

Synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities

Takahiro Takei, Qiang Dong, Yoshinori Yonesaki, Nobuhiro Kumada, Nobukazu Kinomura

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Ternary hybrid film composed of α-zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered α-zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%.

Original language	English
Pages (from-to)	1-9
Number of pages	9
Journal	Polymers
Volume	3
Issue number	1
DOIs	https://doi.org/10.3390/polym3010001
Publication status	Published - 2011 Mar
Externally published	Yes

Keywords

Electrochemical capacitor
Electrodeposition
Graft
Polypyrrole
Zirconium phosphate

ASJC Scopus subject areas

Chemistry(all)
Polymers and Plastics

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10.3390/polym3010001

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title = "Synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities",

abstract = "Ternary hybrid film composed of α-zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered α-zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%.",

keywords = "Electrochemical capacitor, Electrodeposition, Graft, Polypyrrole, Zirconium phosphate",

author = "Takahiro Takei and Qiang Dong and Yoshinori Yonesaki and Nobuhiro Kumada and Nobukazu Kinomura",

year = "2011",

month = mar,

doi = "10.3390/polym3010001",

language = "English",

volume = "3",

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T1 - Synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities

AU - Takei, Takahiro

AU - Dong, Qiang

AU - Yonesaki, Yoshinori

AU - Kumada, Nobuhiro

AU - Kinomura, Nobukazu

PY - 2011/3

Y1 - 2011/3

N2 - Ternary hybrid film composed of α-zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered α-zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%.

AB - Ternary hybrid film composed of α-zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered α-zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%.

KW - Electrochemical capacitor

KW - Electrodeposition

KW - Graft

KW - Polypyrrole

KW - Zirconium phosphate

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DO - 10.3390/polym3010001

M3 - Article

AN - SCOPUS:79851496694

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EP - 9

JO - Polymers

JF - Polymers

SN - 2073-4360

IS - 1

ER -

Synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities

Abstract

Keywords

ASJC Scopus subject areas

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