Synthesis of Pd-Ru solid-solution nanoparticles by pulsed plasma in liquid method

Tsutomu Mashimo, Shota Tamura, Kenta Yamamoto, Zhazgul Kelgenbaeva, Weijan Ma, Makoto Tokuda, Michio Koinuma, Hiroshi Isobe, Akira Yoshiasa

Research output: Contribution to journalArticle

Abstract

We have synthesized solid-solution nanoparticles (Pd : Ru = 1 : 3, 1 : 1 and 3 : 1) in an immiscible Pd-Ru system by the pulsed plasma in liquid method using Pd-Ru mixture bulk electrodes. The particle sizes of the floated and sedimented samples were measured to be <10 and <20 nm, respectively, via high-resolution transmission electron microscopy (HR-TEM). The lattice parameters of nanoparticles followed the Vegard's law, and the energy-dispersive X-ray spectroscopy (EDX) results almost coincided with those obtained for the starting bulk mixtures. The solid-solution structures and local structure were confirmed via HR-TEM, X-ray photoelectron spectroscopy (XPS) and X-ray absorption fine structure spectroscopy (XAFS).

Original languageEnglish
Pages (from-to)13232-13236
Number of pages5
JournalRSC Advances
Volume10
Issue number22
DOIs
Publication statusPublished - 2020 Apr 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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    Mashimo, T., Tamura, S., Yamamoto, K., Kelgenbaeva, Z., Ma, W., Tokuda, M., Koinuma, M., Isobe, H., & Yoshiasa, A. (2020). Synthesis of Pd-Ru solid-solution nanoparticles by pulsed plasma in liquid method. RSC Advances, 10(22), 13232-13236. https://doi.org/10.1039/c9ra10003b