Synthesis of organic capped colloidal zinc oxide quantum dots and their UV dominant emission property

Takahisa Omata, Kazuyuki Takahashi, Shinichi Hashimoto, Yasuhiro Maeda, Katsuhiro Nose, Shinya Otsuka-Yao-Matsuo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A novel synthesis route to organic-capped and colloidal ZnO quantum dots (QDs) has been developed. Specifically, zinc-di-butoxide was hydrolyzed with very dilute water (100∼600 mass ppm) dissolved in hydrophilic benzylamine and polymerized to ZnO by dehydration condensation. After formation of ZnO QDs with 2∼3 nm in diameter, growth of the QDs and exchange the surface capping ligand from hydroxyl groups and/or benzylamine to oleylamine were developed by heating the colloidal solution with oleylamine. The size of the ZnO QDs finally obtained was in the range 3∼5 nm in diameter. The QDs show high dispersibility in various organic solvents. Clear UV emission due to exciton recombination was observed; and its energy was varied according to the quantum size effect from 3.39 to 3.54 eV. By using lithium-free zinc-di-butoxide as a starting material, the defect-related VIS emission was successfully decreased and the UV emission becomes dominant. The influence of water concentration in benzylamine and oleylamine on UV emission intensity was also investigated.

Original languageEnglish
Title of host publicationColloidal Nanoparticles for Electronic Applications - Light Emission, Detection, Photovoltaics, and Transport
Pages31-36
Number of pages6
Publication statusPublished - 2010
Externally publishedYes
Event2009 MRS Fall Meeting - Boston, MA, United States
Duration: 2009 Nov 302009 Dec 4

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1207
ISSN (Print)0272-9172

Other

Other2009 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period09/11/3009/12/4

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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