Synthesis of novel fullerene complex: the [4+2] cycloadduct of (bicyclo[3.2.0]hepta-1,3-dienyl)cobalt(I) complex with C60

Masahiko Iyoda, Fatema Sultana, Shigeru Sasaki, Holger Butenschön

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The thermal reaction of C60 with (η5-bicyclo[3.2.0]hepta-1,3-dienyl)(η4-tetraphenylcyclobutadiene)cobalt(I) produced the Diels-Alder adducts. The X-ray structural analysis of the 1:1 adduct revealed a novel molecular and crystal structure. An interesting redox behavior of the 1:1 adduct is described.

Original languageEnglish
Pages (from-to)579-582
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number4
DOIs
Publication statusPublished - 1995 Jan 23
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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