Synthesis of new lithium- And monoamine-intercalated superconductors Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18) with the dramatically expanded interlayer spacing

Chika Sakamoto; Takashi Noji; Kazuki Sato; Takayuki Kawamata; Masatsune Kato

doi:10.7566/JPSJ.89.115002

Synthesis of new lithium- And monoamine-intercalated superconductors Li_x(C_nH_2n+3N)_yFe_1-zSe (n = 6, 8, 18) with the dramatically expanded interlayer spacing

Chika Sakamoto, Takashi Noji, Kazuki Sato, Takayuki Kawamata, Masatsune Kato

ENG - Applied Physics

Research output: Contribution to journal › Comment/debate › peer-review

3 Citations (Scopus)

Abstract

New superconductors, Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18), have been synthesized via the co-intercalation of linear monoamines together with Li into FeSe. The distance between neighboring Fe layers expands up to 55.7 Å for n = 18, which is much larger than the previous record of 19Å in the FeSe-based intercalation superconductors. Tc remains saturated at ∼42 K.

Original language	English
Article number	115002
Journal	journal of the physical society of japan
Volume	89
Issue number	11
DOIs	https://doi.org/10.7566/JPSJ.89.115002
Publication status	Published - 2020 Nov 15

ASJC Scopus subject areas

Physics and Astronomy(all)

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Synthesis of new lithium- And monoamine-intercalated superconductors Li_x(C_nH_2n+3N)_yFe_1-zSe (n = 6, 8, 18) with the dramatically expanded interlayer spacing. / Sakamoto, Chika; Noji, Takashi; Sato, Kazuki; Kawamata, Takayuki ; Kato, Masatsune.

In: journal of the physical society of japan, Vol. 89, No. 11, 115002, 15.11.2020.

Research output: Contribution to journal › Comment/debate › peer-review

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title = "Synthesis of new lithium- And monoamine-intercalated superconductors Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18) with the dramatically expanded interlayer spacing",

abstract = "New superconductors, Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18), have been synthesized via the co-intercalation of linear monoamines together with Li into FeSe. The distance between neighboring Fe layers expands up to 55.7 {\AA} for n = 18, which is much larger than the previous record of 19{\AA} in the FeSe-based intercalation superconductors. Tc remains saturated at ∼42 K. ",

author = "Chika Sakamoto and Takashi Noji and Kazuki Sato and Takayuki Kawamata and Masatsune Kato",

note = "Funding Information: Acknowledgements This work was supported by JSPS KAKENHI (Grant Numbers 19K05241 and 20K14418). Publisher Copyright: {\textcopyright} 2020 The Physical Society of Japan.",

year = "2020",

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doi = "10.7566/JPSJ.89.115002",

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AU - Sakamoto, Chika

AU - Noji, Takashi

AU - Sato, Kazuki

AU - Kawamata, Takayuki

AU - Kato, Masatsune

PY - 2020/11/15

Y1 - 2020/11/15

N2 - New superconductors, Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18), have been synthesized via the co-intercalation of linear monoamines together with Li into FeSe. The distance between neighboring Fe layers expands up to 55.7 Å for n = 18, which is much larger than the previous record of 19Å in the FeSe-based intercalation superconductors. Tc remains saturated at ∼42 K.

AB - New superconductors, Lix(CnH2n+3N)yFe1-zSe (n = 6, 8, 18), have been synthesized via the co-intercalation of linear monoamines together with Li into FeSe. The distance between neighboring Fe layers expands up to 55.7 Å for n = 18, which is much larger than the previous record of 19Å in the FeSe-based intercalation superconductors. Tc remains saturated at ∼42 K.

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Synthesis of new lithium- And monoamine-intercalated superconductors Li_x(C_nH_2n+3N)_yFe_1-zSe (n = 6, 8, 18) with the dramatically expanded interlayer spacing

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