Synthesis of N-Alkyl/aryl-α/ β-aminoalkylphosphonic acids from organodichloroboranes and α/ β-azidoalkylphosphonates via polyborophosphonates

Jacques Mortier, Ilya D. Gridnev, Anne Dominique Fortineau

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

(formula presented) N-Alkyl/aryl-α-and β-aminoalkylphosphonic acids can be effectively prepared by reductive alkylation of azidoalkylphosphonates with organodichloroboranes. The reaction is accompanied by simultaneous dealkylation of the phosphonates occurring via polyborophosphonates.

Original languageEnglish
Pages (from-to)981-984
Number of pages4
JournalOrganic letters
Volume1
Issue number7
DOIs
Publication statusPublished - 1999 Oct 7
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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