TY - JOUR
T1 - Synthesis of Metal Hydroxide-Layer Silicate Intercalation Compounds (Metal = Mg(II), Ca(II), Mn(II), Fe(II), Co(II), Ni(II), Zn(II), and Cd(II))
AU - Ohtsuka, Kunio
AU - Suda, Mitsuru
AU - Tsunoda, Masakiyo
AU - Ono, Mikiya
PY - 1990/9/1
Y1 - 1990/9/1
N2 - Layer silicate intercalation compounds with metal(II) hydroxide (metal(II) = Mg, Ca, Mn, Fe, Co, Ni, Zn, and Cd) are prepared by adding a base into the metal salt solutions containing layer silicates with cation-exchange properties. The preparation procedures for the intercalates with manganese(II), iron(II), and cobalt(II) hydroxides are conducted under oxygen-free conditions. The hydroxides of these metal cations can crystallize with the cadmium iodide layer structure; the basic unit layer of these metal hydroxides is intercalated into the two-dimensional silicate interlayer region.
AB - Layer silicate intercalation compounds with metal(II) hydroxide (metal(II) = Mg, Ca, Mn, Fe, Co, Ni, Zn, and Cd) are prepared by adding a base into the metal salt solutions containing layer silicates with cation-exchange properties. The preparation procedures for the intercalates with manganese(II), iron(II), and cobalt(II) hydroxides are conducted under oxygen-free conditions. The hydroxides of these metal cations can crystallize with the cadmium iodide layer structure; the basic unit layer of these metal hydroxides is intercalated into the two-dimensional silicate interlayer region.
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U2 - 10.1021/cm00011a009
DO - 10.1021/cm00011a009
M3 - Article
AN - SCOPUS:0001066194
VL - 2
SP - 511
EP - 517
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 5
ER -