Synthesis of hybrid calix[6]arenes having both methylene and epithio bridging groups

Naoya Morohashi, Tomohiro Ishiwata, Kazuaki Ito, Yoshihiro Ohba

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Mono-, tri-, and tetra-thiacalix[6]arene were obtained by acid-catalyzed condensation of the corresponding tetramer and dimer derivatives of p-tert-butylphenol bridged by methylene or sulfur. Replacement of CH 2 by sulfur has significant effect on the properties of calix[6] arene such as the strength of intramolecular hydrogen bonding, inclusion ability toward organic molecules, and conformation properties.

Original languageEnglish
Pages (from-to)799-802
Number of pages4
JournalTetrahedron Letters
Volume45
Issue number4
DOIs
Publication statusPublished - 2004 Jan 19
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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