Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure

Wataru Kosaka, Tohru Ishihara, Hisashi Yashiro, Yayoi Taniguchi, Kazuhito Hashimoto, Shin Ichi Ohkoshi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

We report a crystal structure, bond lengths, and magnetic properties of a Prussian blue analogue, CsCu[Cr(CN) 6]· 2.1H 2O. This compound has a tetragonal structure (I4m2), which is caused by the strong cooperativity due to the Jahn-Teller effect of Cu II and shows ferromagnetism with Curie temperature of 65 K.

Original languageEnglish
Article numberCL-050842
Pages (from-to)1278-1279
Number of pages2
JournalChemistry Letters
Volume34
Issue number9
DOIs
Publication statusPublished - 2005 Sep 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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