Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure

Wataru Kosaka; Tohru Ishihara; Hisashi Yashiro; Yayoi Taniguchi; Kazuhito Hashimoto; Shin Ichi Ohkoshi

doi:10.1246/cl.2005.1278

Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure

Wataru Kosaka, Tohru Ishihara, Hisashi Yashiro, Yayoi Taniguchi, Kazuhito Hashimoto, Shin Ichi Ohkoshi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We report a crystal structure, bond lengths, and magnetic properties of a Prussian blue analogue, CsCu[Cr(CN) ₆]· 2.1H ₂O. This compound has a tetragonal structure (I4m2), which is caused by the strong cooperativity due to the Jahn-Teller effect of Cu ^II and shows ferromagnetism with Curie temperature of 65 K.

Original language	English
Article number	CL-050842
Pages (from-to)	1278-1279
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	9
DOIs	https://doi.org/10.1246/cl.2005.1278
Publication status	Published - 2005 Sept 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure",

abstract = "We report a crystal structure, bond lengths, and magnetic properties of a Prussian blue analogue, CsCu[Cr(CN) 6]· 2.1H 2O. This compound has a tetragonal structure (I4m2), which is caused by the strong cooperativity due to the Jahn-Teller effect of Cu II and shows ferromagnetism with Curie temperature of 65 K.",

author = "Wataru Kosaka and Tohru Ishihara and Hisashi Yashiro and Yayoi Taniguchi and Kazuhito Hashimoto and Ohkoshi, {Shin Ichi}",

year = "2005",

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T1 - Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure

AU - Kosaka, Wataru

AU - Ishihara, Tohru

AU - Yashiro, Hisashi

AU - Taniguchi, Yayoi

AU - Hashimoto, Kazuhito

AU - Ohkoshi, Shin Ichi

PY - 2005/9/5

Y1 - 2005/9/5

N2 - We report a crystal structure, bond lengths, and magnetic properties of a Prussian blue analogue, CsCu[Cr(CN) 6]· 2.1H 2O. This compound has a tetragonal structure (I4m2), which is caused by the strong cooperativity due to the Jahn-Teller effect of Cu II and shows ferromagnetism with Curie temperature of 65 K.

AB - We report a crystal structure, bond lengths, and magnetic properties of a Prussian blue analogue, CsCu[Cr(CN) 6]· 2.1H 2O. This compound has a tetragonal structure (I4m2), which is caused by the strong cooperativity due to the Jahn-Teller effect of Cu II and shows ferromagnetism with Curie temperature of 65 K.

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DO - 10.1246/cl.2005.1278

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Synthesis of ferromagnetic CsCuCr prussian blue analogue with a tetragonal structure

Abstract

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