Synthesis of diamondoids by supercritical xenon discharge plasma

Tomoki Shizuno, Hiroyuki Miyazoe, Koya Saito, Sven Stauss, Minoru Suzuki, Takehiko Sasaki, Kazuo Terashima

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Diamondoids were synthesized by dielectric barrier discharges in supercritical xenon containing dissolved adamantane, which served as a precursor. The synthesis of diamantane was confirmed by gas chromatography mass spectrometry measurements, in addition to energydispersive X-ray spectroscopy and micro-Raman spectroscopy measurements. Moreover, the possible synthesis of two higher-order diamondoids, pentamantane and decamantane, with molecular weights of 330 and 456, respectively, is indicated from the selective ion monitoring mode. The largest production yield was obtained in the vicinity of the critical point.

Original languageEnglish
Article number030207
JournalJapanese journal of applied physics
Volume50
Issue number3
DOIs
Publication statusPublished - 2011 Mar 1
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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  • Cite this

    Shizuno, T., Miyazoe, H., Saito, K., Stauss, S., Suzuki, M., Sasaki, T., & Terashima, K. (2011). Synthesis of diamondoids by supercritical xenon discharge plasma. Japanese journal of applied physics, 50(3), [030207]. https://doi.org/10.1143/JJAP.50.030207