Synthesis of both the enantiomers of hauptmann's periplanone-A and clarification of the structure of Persoons's periplanone-A

Shigefumi Kuwahara; Kenji Mori

doi:10.1016/S0040-4020(01)81465-4

Synthesis of both the enantiomers of hauptmann's periplanone-A and clarification of the structure of Persoons's periplanone-A

Shigefumi Kuwahara, Kenji Mori

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The naturally occurring (-)-enantiomer of Hauptmann's periplanone-A and its stereoisomers were synthesized. Thermal rearrangement of Hauptmann's (-)-periplanone-A by GLC gave Persoons's periplanone-A, the structure of which was determined through an X-ray crystallographic analysis of the corresponding alcohol.

Original language	English
Pages (from-to)	8083-8092
Number of pages	10
Journal	Tetrahedron
Volume	46
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4020(01)81465-4
Publication status	Published - 1990 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4020(01)81465-4

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AB - The naturally occurring (-)-enantiomer of Hauptmann's periplanone-A and its stereoisomers were synthesized. Thermal rearrangement of Hauptmann's (-)-periplanone-A by GLC gave Persoons's periplanone-A, the structure of which was determined through an X-ray crystallographic analysis of the corresponding alcohol.

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Synthesis of both the enantiomers of hauptmann's periplanone-A and clarification of the structure of Persoons's periplanone-A

Abstract

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