Synthesis of both the enantiomers of hauptmann's periplanone-A and clarification of the structure of Persoons's periplanone-A

Shigefumi Kuwahara, Kenji Mori

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The naturally occurring (-)-enantiomer of Hauptmann's periplanone-A and its stereoisomers were synthesized. Thermal rearrangement of Hauptmann's (-)-periplanone-A by GLC gave Persoons's periplanone-A, the structure of which was determined through an X-ray crystallographic analysis of the corresponding alcohol.

Original languageEnglish
Pages (from-to)8083-8092
Number of pages10
JournalTetrahedron
Volume46
Issue number24
DOIs
Publication statusPublished - 1990 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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