Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

Kyoko Tsuji, Yuuichi Fujii, Shigeru Sasaki, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.

Original languageEnglish
Pages (from-to)855-856
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - 1997 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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