Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

Kyoko Tsuji; Yuuichi Fujii; Shigeru Sasaki; Masaaki Yoshifuji

doi:10.1246/cl.1997.855

Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

Kyoko Tsuji, Yuuichi Fujii, Shigeru Sasaki, Masaaki Yoshifuji

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.

Original language	English
Pages (from-to)	855-856
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.1997.855
Publication status	Published - 1997 Jan 1

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abstract = "Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.",

author = "Kyoko Tsuji and Yuuichi Fujii and Shigeru Sasaki and Masaaki Yoshifuji",

year = "1997",

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language = "English",

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T1 - Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

AU - Tsuji, Kyoko

AU - Fujii, Yuuichi

AU - Sasaki, Shigeru

AU - Yoshifuji, Masaaki

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.

AB - Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.

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SN - 0366-7022

IS - 9

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Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

Abstract

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