Synthesis of bis-fused tetrathiafulvalene with mono- and dicarboxylic acids

Takeshi Terauchi, Yuka Kobayashi, Yohji Misaki

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Bis-fused tetrathiafulvalenes with mono- and dicarboxylic acids, 2-{5-(1,3-dithiol-2-ylidene)-[1,3]dithiolo[4,5-d][1,3]dithiol-2-ylidene}-1, 3-dithiole-4-carboxylic acid (1) and 2-{5-(1,3-dithiol-2-ylidene)-[1,3] dithiolo[4,5-d][1,3]dithiol-2-ylidene}-1,3-dithiole-4,5-dicarboxylic acid (2) have been synthesized. The electronic structure of 1 and 2 was examined from their optical absorption spectra and using density-functional calculations.

Original languageEnglish
Pages (from-to)3277-3280
Number of pages4
JournalTetrahedron Letters
Volume53
Issue number26
DOIs
Publication statusPublished - 2012 Jun 27
Externally publishedYes

Keywords

  • Carboxylic acid
  • Electron donor
  • Fused ring
  • Hydrogen bond
  • Supramolecular synthon

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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