Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

Taniyuki Furuyama; Yusuke Sugiya; Nagao Kobayashi

doi:10.1039/c4cc01115e

Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

Taniyuki Furuyama, Yusuke Sugiya, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A μ-oxo dimer of phosphorus(v) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.

Original language	English
Pages (from-to)	4312-4314
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	33
DOIs	https://doi.org/10.1039/c4cc01115e
Publication status	Published - 2014 Mar 27
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c4cc01115e

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title = "Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect",

abstract = "A μ-oxo dimer of phosphorus(v) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.",

author = "Taniyuki Furuyama and Yusuke Sugiya and Nagao Kobayashi",

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AU - Furuyama, Taniyuki

AU - Sugiya, Yusuke

AU - Kobayashi, Nagao

PY - 2014/3/27

Y1 - 2014/3/27

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AB - A μ-oxo dimer of phosphorus(v) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.

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Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

Abstract

ASJC Scopus subject areas

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