Synthesis of a new troponoid liquid crystalline library on solid support

Masashi Hashimoto, Akira Mori, Hitoshi Inoue, Hiroyuki Nagamiya, Takayuki Doi, Takashi Takahashi

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Five types of troponoids including 40 molecules were prepared by means of palladium(0)-catalyzed carbonylation and successive acylation or benzoylation after immobilization of 2-methoxy-5-trifluoromethylsulfonyloxytropone on solid support. Four types of them showed mesophases. The final products have enough purity to detect their mesomorphic properties.

Original languageEnglish
Pages (from-to)1251-1254
Number of pages4
JournalTetrahedron Letters
Volume44
Issue number6
DOIs
Publication statusPublished - 2003 Feb 3
Externally publishedYes

Keywords

  • Pd-catalyzed carbonylation
  • Solid-phase synthesis
  • Troponoid liquid crystals

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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