Abstract
Five types of troponoids including 40 molecules were prepared by means of palladium(0)-catalyzed carbonylation and successive acylation or benzoylation after immobilization of 2-methoxy-5-trifluoromethylsulfonyloxytropone on solid support. Four types of them showed mesophases. The final products have enough purity to detect their mesomorphic properties.
Original language | English |
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Pages (from-to) | 1251-1254 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 44 |
Issue number | 6 |
DOIs | |
Publication status | Published - 2003 Feb 3 |
Externally published | Yes |
Keywords
- Pd-catalyzed carbonylation
- Solid-phase synthesis
- Troponoid liquid crystals
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry