Synthesis of a cyclic dimer of dibenzo-18-crown-6 containing rigid 4,4′-bis(aminomethyl) biphenyl spacer

Bing Zhu Yin; Tie Chen; Kazushi Kinbara; Takeshi Wata; Kazuhiko Saigo

Synthesis of a cyclic dimer of dibenzo-18-crown-6 containing rigid 4,4′-bis(aminomethyl) biphenyl spacer

Bing Zhu Yin, Tie Chen, Kazushi Kinbara, Takeshi Wata, Kazuhiko Saigo

Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Reaction of diacyl chloride (1) with diaminodibenzo-18-crown-6 (2) under high dilution conditions gave macrocyclic diamide (3) in good yield. 3 was reduced in toluene with SMEAH [sodium bis (2-methoxyethoxy) aluminum hydride] to afford the target macrocyclic compounds 4. The week π-electronic donor-acceptor interaction between 4 and [60] fullerene was found.

Original language	English
Pages (from-to)	1030-1033
Number of pages	4
Journal	Chinese Journal of Organic Chemistry
Volume	22
Issue number	12
Publication status	Published - 2002 Dec 1

Keywords

Cyclic dimer of dibenzo-18-crown-6
SMEAH reduction
[60]fullerene

ASJC Scopus subject areas

Organic Chemistry

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title = "Synthesis of a cyclic dimer of dibenzo-18-crown-6 containing rigid 4,4′-bis(aminomethyl) biphenyl spacer",

abstract = "Reaction of diacyl chloride (1) with diaminodibenzo-18-crown-6 (2) under high dilution conditions gave macrocyclic diamide (3) in good yield. 3 was reduced in toluene with SMEAH [sodium bis (2-methoxyethoxy) aluminum hydride] to afford the target macrocyclic compounds 4. The week π-electronic donor-acceptor interaction between 4 and [60] fullerene was found.",

keywords = "Cyclic dimer of dibenzo-18-crown-6, SMEAH reduction, [60]fullerene",

author = "Yin, {Bing Zhu} and Tie Chen and Kazushi Kinbara and Takeshi Wata and Kazuhiko Saigo",

year = "2002",

month = dec,

day = "1",

language = "English",

volume = "22",

pages = "1030--1033",

journal = "Chinese Journal of Organic Chemistry",

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TY - JOUR

T1 - Synthesis of a cyclic dimer of dibenzo-18-crown-6 containing rigid 4,4′-bis(aminomethyl) biphenyl spacer

AU - Yin, Bing Zhu

AU - Chen, Tie

AU - Kinbara, Kazushi

AU - Wata, Takeshi

AU - Saigo, Kazuhiko

PY - 2002/12/1

Y1 - 2002/12/1

N2 - Reaction of diacyl chloride (1) with diaminodibenzo-18-crown-6 (2) under high dilution conditions gave macrocyclic diamide (3) in good yield. 3 was reduced in toluene with SMEAH [sodium bis (2-methoxyethoxy) aluminum hydride] to afford the target macrocyclic compounds 4. The week π-electronic donor-acceptor interaction between 4 and [60] fullerene was found.

AB - Reaction of diacyl chloride (1) with diaminodibenzo-18-crown-6 (2) under high dilution conditions gave macrocyclic diamide (3) in good yield. 3 was reduced in toluene with SMEAH [sodium bis (2-methoxyethoxy) aluminum hydride] to afford the target macrocyclic compounds 4. The week π-electronic donor-acceptor interaction between 4 and [60] fullerene was found.

KW - Cyclic dimer of dibenzo-18-crown-6

KW - SMEAH reduction

KW - [60]fullerene

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M3 - Article

AN - SCOPUS:0036928245

VL - 22

SP - 1030

EP - 1033

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

SN - 0253-2786

IS - 12

ER -

Synthesis of a cyclic dimer of dibenzo-18-crown-6 containing rigid 4,4′-bis(aminomethyl) biphenyl spacer

Abstract

Keywords

ASJC Scopus subject areas

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