Abstract
Reaction of diacyl chloride (1) with diaminodibenzo-18-crown-6 (2) under high dilution conditions gave macrocyclic diamide (3) in good yield. 3 was reduced in toluene with SMEAH [sodium bis (2-methoxyethoxy) aluminum hydride] to afford the target macrocyclic compounds 4. The week π-electronic donor-acceptor interaction between 4 and [60] fullerene was found.
Original language | English |
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Pages (from-to) | 1030-1033 |
Number of pages | 4 |
Journal | Chinese Journal of Organic Chemistry |
Volume | 22 |
Issue number | 12 |
Publication status | Published - 2002 Dec 1 |
Keywords
- Cyclic dimer of dibenzo-18-crown-6
- SMEAH reduction
- [60]fullerene
ASJC Scopus subject areas
- Organic Chemistry