Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex

Shin Ya Tashita, Takahito Watanabe, Hiromi Tobita

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

An NHC-stabilized (chlorogermyl)metallogermylene [Cp- (CO) 3WGe{GeCl(Mes)2}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2]- [CpW(CO)3] (dme: 1,2-dimethoxyethane) with (chlorogermyl)- chlorogermylene [GeCl{GeCl(Mes) 2}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp- (CO)2W=Ge{GeCl(Mes)2}(MeIiPr)].

Original languageEnglish
Pages (from-to)43-44
Number of pages2
JournalChemistry Letters
Volume42
Issue number1
DOIs
Publication statusPublished - 2013 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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