Synthesis of 13-methyl[10] (4,6)pyrimidinophane

Takao Sakamoto, Sumiko Nishimura, Yoshinori Kondo, Hiroshi Yamanaka

Research output: Contribution to journalArticle

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Abstract

The palladium-catalyzed reaction of 4,6-diiodo-2-methylpyrimidine with 5-trimethylsilylpent-4-yn-1-ylzinc iodide gave 4,6-bis(5-trimethylsilylpent-4-yn-1-yl)-2-methyl-pyrimidine. Desilylation of the product followed by treatment with cupric acetate gave 13-methyl[10](4,6)pyrimidinophane.

Original languageEnglish
Pages (from-to)475-478
Number of pages4
JournalHeterocycles
Volume27
Issue number2
Publication statusPublished - 1988 Feb 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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  • Cite this

    Sakamoto, T., Nishimura, S., Kondo, Y., & Yamanaka, H. (1988). Synthesis of 13-methyl[10] (4,6)pyrimidinophane. Heterocycles, 27(2), 475-478.