Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

Nagao Kobayashi; T. Naito; T. Inabe

doi:10.1016/S0379-6779(00)01530-7

Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

Nagao Kobayashi, T. Naito, T. Inabe

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A novel dimerized Ni-dithiolene complex, (n-Bu₄N)₂[Ni(dmit)(i-mnt)]₂, was synthesized and characterized by X-ray structure analysis. In this complex two [Ni(dmit)(i-mnt)] units were mutually connected by two long axial Ni-S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mnt)]₂^2- were prepared by electrocrystallization and characterized by X-ray analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature resistivity ρ_rt/Ωcm = 10², 10³, respectively.

Original language	English
Pages (from-to)	1055-1056
Number of pages	2
Journal	Synthetic Metals
Volume	120
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(00)01530-7
Publication status	Published - 2001 Mar 15

Keywords

Electrocrystallization
Organic semiconductors
X-ray diffraction

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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title = "Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure",

abstract = "A novel dimerized Ni-dithiolene complex, (n-Bu4N)2[Ni(dmit)(i-mnt)]2, was synthesized and characterized by X-ray structure analysis. In this complex two [Ni(dmit)(i-mnt)] units were mutually connected by two long axial Ni-S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mnt)]22- were prepared by electrocrystallization and characterized by X-ray analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature resistivity ρrt/Ωcm = 102, 103, respectively.",

keywords = "Electrocrystallization, Organic semiconductors, X-ray diffraction",

author = "Nagao Kobayashi and T. Naito and T. Inabe",

year = "2001",

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doi = "10.1016/S0379-6779(00)01530-7",

language = "English",

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journal = "Synthetic Metals",

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T1 - Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

AU - Kobayashi, Nagao

AU - Naito, T.

AU - Inabe, T.

PY - 2001/3/15

Y1 - 2001/3/15

N2 - A novel dimerized Ni-dithiolene complex, (n-Bu4N)2[Ni(dmit)(i-mnt)]2, was synthesized and characterized by X-ray structure analysis. In this complex two [Ni(dmit)(i-mnt)] units were mutually connected by two long axial Ni-S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mnt)]22- were prepared by electrocrystallization and characterized by X-ray analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature resistivity ρrt/Ωcm = 102, 103, respectively.

AB - A novel dimerized Ni-dithiolene complex, (n-Bu4N)2[Ni(dmit)(i-mnt)]2, was synthesized and characterized by X-ray structure analysis. In this complex two [Ni(dmit)(i-mnt)] units were mutually connected by two long axial Ni-S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mnt)]22- were prepared by electrocrystallization and characterized by X-ray analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature resistivity ρrt/Ωcm = 102, 103, respectively.

KW - Electrocrystallization

KW - Organic semiconductors

KW - X-ray diffraction

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U2 - 10.1016/S0379-6779(00)01530-7

DO - 10.1016/S0379-6779(00)01530-7

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EP - 1056

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1-3

ER -

Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

Abstract

Keywords

ASJC Scopus subject areas

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