Synthesis, electrical properties of a novel Ni-dithiolene complex with dimerized structure

Nagao Kobayashi, T. Naito, T. Inabe

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A novel dimerized Ni-dithiolene complex, (n-Bu4N)2[Ni(dmit)(i-mnt)]2, was synthesized and characterized by X-ray structure analysis. In this complex two [Ni(dmit)(i-mnt)] units were mutually connected by two long axial Ni-S bonds. The single crystals of BEDT-TTF and TTF salts with [Ni(dmit)(i-mnt)]22- were prepared by electrocrystallization and characterized by X-ray analysis. The Ni-S bonds of each dimer were also retained in both salts. Both salts exhibited semiconducting behavior with the room-temperature resistivity ρrt/Ωcm = 102, 103, respectively.

Original languageEnglish
Pages (from-to)1055-1056
Number of pages2
JournalSynthetic Metals
Volume120
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15

Keywords

  • Electrocrystallization
  • Organic semiconductors
  • X-ray diffraction

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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