Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex

Li Na Zheng, Bin Hu, Wen Qian Chen, Yan Mei Chen, Tao Lei, Ya Hong Li

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A complex of the composition [Ni2(Hpyco)2(pa)(EtOH)Cl3] (1) (Hpyco =pyridine-2-carbaldehyde oxime; Hpa=2-picolinic acid) has been synthesized via solvothermal synthetic method, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure analysis revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni (II) ion displaying pseudo-octahedron geometry. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Ni(II) & Ni(II) interactions. CCDC: 806916.

Original languageEnglish
Pages (from-to)2162-2166
Number of pages5
JournalChinese Journal of Inorganic Chemistry
Volume27
Issue number11
Publication statusPublished - 2011 Nov 1

Keywords

  • 2-picolinic acid
  • Crystal structure
  • Dinuclear Ni(II) complex
  • Magnetic property
  • Mixed-bridged
  • Pyridine-2-carbaldehyde oxime

ASJC Scopus subject areas

  • Inorganic Chemistry

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