Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex

Li Na Zheng; Bin Hu; Wen Qian Chen; Yan Mei Chen; Tao Lei; Ya Hong Li

Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex

Li Na Zheng, Bin Hu, Wen Qian Chen, Yan Mei Chen, Tao Lei, Ya Hong Li

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A complex of the composition [Ni₂(Hpyco)₂(pa)(EtOH)Cl₃] (1) (Hpyco =pyridine-2-carbaldehyde oxime; Hpa=2-picolinic acid) has been synthesized via solvothermal synthetic method, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure analysis revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni (II) ion displaying pseudo-octahedron geometry. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Ni(II) & Ni(II) interactions. CCDC: 806916.

Original language	English
Pages (from-to)	2162-2166
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	27
Issue number	11
Publication status	Published - 2011 Nov 1

Keywords

2-picolinic acid
Crystal structure
Dinuclear Ni(II) complex
Magnetic property
Mixed-bridged
Pyridine-2-carbaldehyde oxime

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex",

abstract = "A complex of the composition [Ni2(Hpyco)2(pa)(EtOH)Cl3] (1) (Hpyco =pyridine-2-carbaldehyde oxime; Hpa=2-picolinic acid) has been synthesized via solvothermal synthetic method, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure analysis revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni (II) ion displaying pseudo-octahedron geometry. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Ni(II) & Ni(II) interactions. CCDC: 806916.",

keywords = "2-picolinic acid, Crystal structure, Dinuclear Ni(II) complex, Magnetic property, Mixed-bridged, Pyridine-2-carbaldehyde oxime",

author = "Zheng, {Li Na} and Bin Hu and Chen, {Wen Qian} and Chen, {Yan Mei} and Tao Lei and Li, {Ya Hong}",

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language = "English",

volume = "27",

pages = "2162--2166",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex

AU - Zheng, Li Na

AU - Hu, Bin

AU - Chen, Wen Qian

AU - Chen, Yan Mei

AU - Lei, Tao

AU - Li, Ya Hong

PY - 2011/11/1

Y1 - 2011/11/1

N2 - A complex of the composition [Ni2(Hpyco)2(pa)(EtOH)Cl3] (1) (Hpyco =pyridine-2-carbaldehyde oxime; Hpa=2-picolinic acid) has been synthesized via solvothermal synthetic method, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure analysis revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni (II) ion displaying pseudo-octahedron geometry. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Ni(II) & Ni(II) interactions. CCDC: 806916.

AB - A complex of the composition [Ni2(Hpyco)2(pa)(EtOH)Cl3] (1) (Hpyco =pyridine-2-carbaldehyde oxime; Hpa=2-picolinic acid) has been synthesized via solvothermal synthetic method, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure analysis revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni (II) ion displaying pseudo-octahedron geometry. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Ni(II) & Ni(II) interactions. CCDC: 806916.

KW - 2-picolinic acid

KW - Crystal structure

KW - Dinuclear Ni(II) complex

KW - Magnetic property

KW - Mixed-bridged

KW - Pyridine-2-carbaldehyde oxime

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M3 - Article

AN - SCOPUS:80855131072

VL - 27

SP - 2162

EP - 2166

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

SN - 1001-4861

IS - 11

ER -

Synthesis, crystal structure and magnetic property of a mixed-bridged dinuclear Ni(II) complex

Abstract

Keywords

ASJC Scopus subject areas

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