Synthesis and UV-shielding properties of ZnO- and CaO-doped CeO2 via soft solution chemical process

Ruixing Li, Shinryo Yabe, Mika Yamashita, Shigeyosi Momose, Sakae Yoshida, Shu Yin, Tsugio Sato

    Research output: Contribution to journalConference articlepeer-review

    219 Citations (Scopus)

    Abstract

    Fine particles of ZnO- and CaO-doped CeO2 for use as an ultraviolet (UV) filter were synthesized via soft solution chemical processes at 40 °C and final pH 5-6. Especially, Ce1 - xZnxO2 - x solid solutions were systematically investigated in a wide ZnO concentration range for the first time and the solubility limit of ZnO in a fluorite structure was suggested to be x = 0.561. Minor CaO solubility in ceria was observed under present reaction conditions (pH 5-6). Novel nanoparticles with significantly reduced oxidation catalytic activity, as well as excellent UV-absorption capability were obtained by doping ZnO or CaO in CeO2.

    Original languageEnglish
    Pages (from-to)235-241
    Number of pages7
    JournalSolid State Ionics
    Volume151
    Issue number1-4
    DOIs
    Publication statusPublished - 2002 Nov 1
    EventSSP- 2000 - Tokyo, Japan
    Duration: 2000 Dec 112000 Dec 13

    Keywords

    • Ceria
    • Dopants
    • Nanoparticles
    • Soft solution process
    • UV-shielding

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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