Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

Kyohei Hayashi, Mitsuharu Nakatani, Akito Hayashi, Masato Takano, Masaaki Okazaki, Kozo Toyota, Masaaki Yoshifuji, Fumiyuki Ozawa

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.

Original languageEnglish
Pages (from-to)1970-1972
Number of pages3
JournalOrganometallics
Volume27
Issue number9
DOIs
Publication statusPublished - 2008 May 12

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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