Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

Kyohei Hayashi; Mitsuharu Nakatani; Akito Hayashi; Masato Takano; Masaaki Okazaki; Kozo Toyota; Masaaki Yoshifuji; Fumiyuki Ozawa

doi:10.1021/om800163p

Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

Kyohei Hayashi, Mitsuharu Nakatani, Akito Hayashi, Masato Takano, Masaaki Okazaki, Kozo Toyota, Masaaki Yoshifuji, Fumiyuki Ozawa

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.

Original language	English
Pages (from-to)	1970-1972
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	9
DOIs	https://doi.org/10.1021/om800163p
Publication status	Published - 2008 May 12

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems",

abstract = "1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.",

author = "Kyohei Hayashi and Mitsuharu Nakatani and Akito Hayashi and Masato Takano and Masaaki Okazaki and Kozo Toyota and Masaaki Yoshifuji and Fumiyuki Ozawa",

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T1 - Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

AU - Hayashi, Kyohei

AU - Nakatani, Mitsuharu

AU - Hayashi, Akito

AU - Takano, Masato

AU - Okazaki, Masaaki

AU - Toyota, Kozo

AU - Yoshifuji, Masaaki

AU - Ozawa, Fumiyuki

PY - 2008/5/12

Y1 - 2008/5/12

N2 - 1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.

AB - 1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)-(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.

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EP - 1972

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 9

ER -

Synthesis and structures of platinum(0) alkyne complexes with extended π-conjugated systems

Abstract

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