Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]23-S2)W(CO)5 and Cp2Fe2(CO)3(μ-CO)(μ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex

Katsuaki Kuge, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalShort surveypeer-review

8 Citations (Scopus)

Abstract

The reaction of CpFe(CO)2Br, NaSH and W(CO)5(THF) gave two Fe2W clusters, one with a μ3-S2 and the other with a μ3-S; in the former cluster W(CO)5 moiety migration on the disulfido ligand was observed by variable-temperature 1H NMR spectroscopy.

Original languageEnglish
Pages (from-to)1061-1062
Number of pages2
JournalChemical Communications
Issue number12
DOIs
Publication statusPublished - 1999 Jun 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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