Synthesis and structure of thiophene, selenophene, and related compounds carrying four phosphoryl groups

Shigeru Sasaki, Kazutaka Adachi, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

Abstract

Dihydrotetraphosphorylthiophene 2 was syntheiszed by the addition of sodium hydrosulfide to 2 equivalents of diphosphorylacetylene 1 followed by cyclization. Oxidation of 2 with mCPBA afforded tetraphosphorylthiophene 3. The corresponding selenium compounds 4 and 5 were analogously synthesized.

Original languageEnglish
Number of pages1
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume183
Issue number2-3
DOIs
Publication statusPublished - 2008 Feb 1

Keywords

  • Dihydrothiophene
  • Phosphoryl group
  • Thiophene

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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