Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex

Tamiko Takeuchi, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalLetterpeer-review

51 Citations (Scopus)

Abstract

The first manganese derivative of the donor-stabilized bis(silylene) complex (OC)4Mn{SiMe2⋯O(Me)⋯ SiMe2} has been synthesized by the photolysis of (OC)5MnSiMe2SiMe2OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi2O chelate ring.

Original languageEnglish
Pages (from-to)835-836
Number of pages2
JournalOrganometallics
Volume10
Issue number4
DOIs
Publication statusPublished - 1991 Apr 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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