Synthesis and structure of a base-stabilized silyl(silylene)tantalum complex

Hidenori Koshikawa; Masaaki Okazaki; Shun Ichi Matsumoto; Keiji Ueno; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.2005.1412

Synthesis and structure of a base-stabilized silyl(silylene)tantalum complex

Hidenori Koshikawa, Masaaki Okazaki, Shun Ichi Matsumoto, Keiji Ueno, Hiromi Tobita, Hiroshi Ogino

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Thermal reaction of Cp₂Ta(η²-C₃H ₆) with HSiMe₂SiMe₂-OMe in toluene at 60°C gave Cp₂Ta{SiMe₂⋯O(Me)⋯SiMe₂} (7%) and Cp₂TaH(SiMe₂SiMe₂OMe)₂ (8%). The former methoxy-stabilized silyl(silylene) complex was characterized by X-ray diffraction study.

Original language	English
Pages (from-to)	1412-1413
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	10
DOIs	https://doi.org/10.1246/cl.2005.1412
Publication status	Published - 2005 Oct 5

ASJC Scopus subject areas

Chemistry(all)

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title = "Synthesis and structure of a base-stabilized silyl(silylene)tantalum complex",

abstract = "Thermal reaction of Cp2Ta(η2-C3H 6) with HSiMe2SiMe2-OMe in toluene at 60°C gave Cp2Ta{SiMe2⋯O(Me)⋯SiMe2} (7%) and Cp2TaH(SiMe2SiMe2OMe)2 (8%). The former methoxy-stabilized silyl(silylene) complex was characterized by X-ray diffraction study.",

author = "Hidenori Koshikawa and Masaaki Okazaki and Matsumoto, {Shun Ichi} and Keiji Ueno and Hiromi Tobita and Hiroshi Ogino",

year = "2005",

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doi = "10.1246/cl.2005.1412",

language = "English",

volume = "34",

pages = "1412--1413",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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TY - JOUR

T1 - Synthesis and structure of a base-stabilized silyl(silylene)tantalum complex

AU - Koshikawa, Hidenori

AU - Okazaki, Masaaki

AU - Matsumoto, Shun Ichi

AU - Ueno, Keiji

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 2005/10/5

Y1 - 2005/10/5

N2 - Thermal reaction of Cp2Ta(η2-C3H 6) with HSiMe2SiMe2-OMe in toluene at 60°C gave Cp2Ta{SiMe2⋯O(Me)⋯SiMe2} (7%) and Cp2TaH(SiMe2SiMe2OMe)2 (8%). The former methoxy-stabilized silyl(silylene) complex was characterized by X-ray diffraction study.

AB - Thermal reaction of Cp2Ta(η2-C3H 6) with HSiMe2SiMe2-OMe in toluene at 60°C gave Cp2Ta{SiMe2⋯O(Me)⋯SiMe2} (7%) and Cp2TaH(SiMe2SiMe2OMe)2 (8%). The former methoxy-stabilized silyl(silylene) complex was characterized by X-ray diffraction study.

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

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