Synthesis and structure of [η4- tetrakis(arylethoxyphosphoryl)cyclobutadiene]-(η5- cyclopentadienyl)cobalt(I) complexes

Shigeru Sasaki, Kiyotoshi Kato, Yoshihiro Tanabe, Masaaki Yoshifuji

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8 Citations (Scopus)

Abstract

4-Tetrakis(arylethoxyphosphoryl)cyclobutadiene] (η5-cyclopentadienyl)cobalt(I) complexes were synthesized by reaction of bis(arylethoxyphosphoryl)acetylenes with CpCo(CO)2 and several diastereomers were isolated. Whole molecular structure of the tetraphosphorylcyclobutadiene complex was significantly affected by relative configuration of the phosphoryl groups.

Original languageEnglish
Pages (from-to)1004-1005
Number of pages2
JournalChemistry Letters
Volume33
Issue number8
DOIs
Publication statusPublished - 2004 Aug 5

ASJC Scopus subject areas

  • Chemistry(all)

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