Synthesis and structural analysis of lithium nickel vanadate

M. S. Bhuvaneswari; S. Selvasekarapandian; O. Kamishima; Junichi Kawamura; T. Hattori

doi:10.1016/j.matchemphys.2004.10.054

Synthesis and structural analysis of lithium nickel vanadate

M. S. Bhuvaneswari, S. Selvasekarapandian, O. Kamishima, Junichi Kawamura, T. Hattori

Division of Inorganic Material Research

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The compound Li_xNiVO₄ (x = 0.8; 1.0; 1.2) has been prepared by a solid state reaction method at 800 °C. The X-ray diffraction pattern of Li_1.2NiVO₄ shows the absence of the (1 1 1) line, indicating the occupation of more vanadium ions on the tetrahedrally coordinated interstices. The averaged size of the particles and the grain size have been found to be around 2-10 μm. The grain interior and grain boundary resistance values are found to be 4.08 × 10⁵ and 1.45 × 10⁶ Ω cm^-1 at 573 K. The formal activation energy, describing the temperature dependence of conductivity of Li _0.8NiVO₄, was found to be 0.64 eV.

Original language	English
Pages (from-to)	94-98
Number of pages	5
Journal	Materials Chemistry and Physics
Volume	91
Issue number	1
DOIs	https://doi.org/10.1016/j.matchemphys.2004.10.054
Publication status	Published - 2005 May 15

Keywords

Impedance spectroscopy
Inverse spinel
Lithium nickel vanadate
Particle size analysis

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/j.matchemphys.2004.10.054

Cite this

@article{232f9f160f624f0fbed8a318fa57e462,

title = "Synthesis and structural analysis of lithium nickel vanadate",

abstract = "The compound LixNiVO4 (x = 0.8; 1.0; 1.2) has been prepared by a solid state reaction method at 800 °C. The X-ray diffraction pattern of Li1.2NiVO4 shows the absence of the (1 1 1) line, indicating the occupation of more vanadium ions on the tetrahedrally coordinated interstices. The averaged size of the particles and the grain size have been found to be around 2-10 μm. The grain interior and grain boundary resistance values are found to be 4.08 × 105 and 1.45 × 106 Ω cm-1 at 573 K. The formal activation energy, describing the temperature dependence of conductivity of Li 0.8NiVO4, was found to be 0.64 eV.",

keywords = "Impedance spectroscopy, Inverse spinel, Lithium nickel vanadate, Particle size analysis",

author = "Bhuvaneswari, {M. S.} and S. Selvasekarapandian and O. Kamishima and Junichi Kawamura and T. Hattori",

year = "2005",

month = may,

day = "15",

doi = "10.1016/j.matchemphys.2004.10.054",

language = "English",

volume = "91",

pages = "94--98",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier BV",

number = "1",

}

TY - JOUR

T1 - Synthesis and structural analysis of lithium nickel vanadate

AU - Bhuvaneswari, M. S.

AU - Selvasekarapandian, S.

AU - Kamishima, O.

AU - Kawamura, Junichi

AU - Hattori, T.

PY - 2005/5/15

Y1 - 2005/5/15

N2 - The compound LixNiVO4 (x = 0.8; 1.0; 1.2) has been prepared by a solid state reaction method at 800 °C. The X-ray diffraction pattern of Li1.2NiVO4 shows the absence of the (1 1 1) line, indicating the occupation of more vanadium ions on the tetrahedrally coordinated interstices. The averaged size of the particles and the grain size have been found to be around 2-10 μm. The grain interior and grain boundary resistance values are found to be 4.08 × 105 and 1.45 × 106 Ω cm-1 at 573 K. The formal activation energy, describing the temperature dependence of conductivity of Li 0.8NiVO4, was found to be 0.64 eV.

AB - The compound LixNiVO4 (x = 0.8; 1.0; 1.2) has been prepared by a solid state reaction method at 800 °C. The X-ray diffraction pattern of Li1.2NiVO4 shows the absence of the (1 1 1) line, indicating the occupation of more vanadium ions on the tetrahedrally coordinated interstices. The averaged size of the particles and the grain size have been found to be around 2-10 μm. The grain interior and grain boundary resistance values are found to be 4.08 × 105 and 1.45 × 106 Ω cm-1 at 573 K. The formal activation energy, describing the temperature dependence of conductivity of Li 0.8NiVO4, was found to be 0.64 eV.

KW - Impedance spectroscopy

KW - Inverse spinel

KW - Lithium nickel vanadate

KW - Particle size analysis

UR - http://www.scopus.com/inward/record.url?scp=13444293180&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=13444293180&partnerID=8YFLogxK

U2 - 10.1016/j.matchemphys.2004.10.054

DO - 10.1016/j.matchemphys.2004.10.054

M3 - Article

AN - SCOPUS:13444293180

VL - 91

SP - 94

EP - 98

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

IS - 1

ER -

Synthesis and structural analysis of lithium nickel vanadate

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this