Synthesis and stereochemical confirmation of the cis-fused L/M and N/O ring systems of maitotoxin

Makoto Sasaki, Taro Nonomura, Michio Murata, Kazuo Tachibana

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished. Comparison of its 1H and 13C NMR data with those of the natural toxin established the earlier stereochemical assignments.

Original languageEnglish
Pages (from-to)5023-5026
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number28
DOIs
Publication statusPublished - 1994 Jul 11
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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