Synthesis and spectral properties of nonclassical binuclear thienoporphyrazines

Tatiana V. Dubinina, Nataliya E. Borisova, Marina V. Sedova, Larisa G. Tomilova, Taniyuki Furuyama, Nagao Kobayashi

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The first examples of planar binuclear porphyrazines sharing a common benzene or naphthalene ring based on a 3,4-thiophene moiety have been synthesized and characterized using nuclear magnetic resonance spectroscopy, high-resolution mass spectrometry, electronic absorption spectroscopy and magnetic circular dichroism. In order to enhance the interpretation of the electronic structures, quantum chemical studies were carried out. The formation of nanoaggregates in a solid film was shown using atomic force microscopy.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalDyes and Pigments
Volume117
DOIs
Publication statusPublished - 2015 Jan 1

Keywords

  • AFM
  • Binuclear complex
  • MCD
  • Porphyrazine
  • Thiophene
  • UV-Vis spectroscopy

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Process Chemistry and Technology

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