Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki; Midori Murakami; Masaaki Yoshifuji

doi:10.1080/10426507.2018.1547728

Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki, Midori Murakami, Masaaki Yoshifuji

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

Original language	English
Pages (from-to)	598-601
Number of pages	4
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	194
Issue number	4-6
DOIs	https://doi.org/10.1080/10426507.2018.1547728
Publication status	Published - 2019 May 27

Keywords

Phosphine
cyclic voltammogram
phenothiazine
triarylphosphine

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426507.2018.1547728

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abstract = "The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.",

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author = "Shigeru Sasaki and Midori Murakami and Masaaki Yoshifuji",

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AU - Sasaki, Shigeru

AU - Murakami, Midori

AU - Yoshifuji, Masaaki

PY - 2019/5/27

Y1 - 2019/5/27

N2 - The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

AB - The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

KW - Phosphine

KW - cyclic voltammogram

KW - phenothiazine

KW - triarylphosphine

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JO - Phosphorus, Sulfur and Silicon and the Related Elements

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SN - 1042-6507

IS - 4-6

ER -

Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Abstract

Keywords

ASJC Scopus subject areas

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