Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki; Midori Murakami; Masaaki Yoshifuji

doi:10.1080/10426507.2018.1547728

Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki, Midori Murakami, Masaaki Yoshifuji

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

Original language	English
Pages (from-to)	598-601
Number of pages	4
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	194
Issue number	4-6
DOIs	https://doi.org/10.1080/10426507.2018.1547728
Publication status	Published - 2019 May 27

Keywords

Phosphine
cyclic voltammogram
phenothiazine
triarylphosphine

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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KW - cyclic voltammogram

KW - phenothiazine

KW - triarylphosphine

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