Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki, Midori Murakami, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

Original languageEnglish
Pages (from-to)598-601
Number of pages4
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume194
Issue number4-6
DOIs
Publication statusPublished - 2019 May 27

Keywords

  • Phosphine
  • cyclic voltammogram
  • phenothiazine
  • triarylphosphine

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties'. Together they form a unique fingerprint.

Cite this