Abstract
The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.
Original language | English |
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Pages (from-to) | 598-601 |
Number of pages | 4 |
Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
Volume | 194 |
Issue number | 4-6 |
DOIs | |
Publication status | Published - 2019 May 27 |
Keywords
- Phosphine
- cyclic voltammogram
- phenothiazine
- triarylphosphine
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Inorganic Chemistry