Synthesis and Redox Behavior of a Sheathed Cross-Conjugated Polythiophene

Kazunori Sugiyasu, Ryota Inoue, Ryo Shomura, Yoshitaka Matsushita, Masayuki Takeuchi

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Control over the electronic structure in π-conjugated polymers is of great importance for the development of organic electronics and spintronics. In this study, we synthesized a sheathed cross-conjugated polythiophene through oxidative electrochemical polymerization. Spectroelectrochemistry has revealed that unlike linearly conjugated polythiophenes, polarons were confined in the repeating units that were segmented by cross-conjugation.

Original languageEnglish
Article numberst-2018-u0527-c
Pages (from-to)2557-2561
Number of pages5
JournalSynlett
Volume29
Issue number19
DOIs
Publication statusPublished - 2018
Externally publishedYes

Keywords

  • cross-conjugation
  • insulated molecular wires
  • polythiophenes

ASJC Scopus subject areas

  • Organic Chemistry

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