Synthesis and reactions of 4-tributylstannyl-3-methylisoxazole

Daishi Uchiyama, Makoto Yabe, Hiroshi Kameyama, Takao Sakamoto, Yoshinori Kondo, Hiroshi Yamanaka

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16 Citations (Scopus)

Abstract

1,3-Dipolar cycloaddition reaction of bis(tributylstannyl)acetylene with nitrile oxides, followed by treatment with aqueous ammonia in ethanol in a sealed tube gave 4-tributylstannyl-3-methylisoxazole. The palladium catalyzed cross coupling reaction of the isoxazole with 2-iodonitrobenzene, followed by reductive cyclization afforded 3-acetylindole.

Original languageEnglish
Pages (from-to)1301-1304
Number of pages4
JournalHeterocycles
Volume43
Issue number6
DOIs
Publication statusPublished - 1996

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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  • Cite this

    Uchiyama, D., Yabe, M., Kameyama, H., Sakamoto, T., Kondo, Y., & Yamanaka, H. (1996). Synthesis and reactions of 4-tributylstannyl-3-methylisoxazole. Heterocycles, 43(6), 1301-1304. https://doi.org/10.3987/com-96-7489